Description: Synergy Between Dynamics and Reactivity at Clusters and Surfaces, Paperback by Farrugia, L. J. (EDT), ISBN 9401040605, ISBN-13 9789401040600, Brand New, Free shipping in the US The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has born fruit in the use of well defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in The Synergy between Dynamics and Reactivity at Clusters and Surfaces are: (1) Mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces. The role of metal-metal bond breaking in diffusion. (2) Analogies in the structure of chemisorbed species and related ligands on metallic clusters. (3) Analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions. (4) The role of mobile precursors for dissociation of chemisorption on extended metals and on clusters. Are there analogies in the ligand attachment during cluster compound synthesis? (5) The role of defect sites on metal surfaces in catalyzing chemical reactions and the connection to the special bonding properties of sites on metal clusters having lowest metal-metal coordination. (6) The size of metal clusters needed to mimic surface phenomena on bulk metal surfaces. Different sites needed for different phenomena.
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Book Title: Synergy Between Dynamics and Reactivity at Clusters and Surfaces
Number of Pages: VIII, 368 Pages
Publication Name: Synergy between Dynamics and Reactivity at Clusters and Surfaces
Language: English
Publisher: Springer Netherlands
Subject: Chemistry / Physical & Theoretical, Chemistry / Inorganic, Chemistry / Organic
Publication Year: 2012
Type: Textbook
Item Weight: 21.4 Oz
Item Length: 9.4 in
Author: L. J. Farrugia
Subject Area: Science
Series: NATO Science Series C: Ser.
Item Width: 6.3 in
Format: Trade Paperback
